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Germanium(IV) chloride

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Formula: Cl4Ge
CAS: 10038-98-9
search Element: germanium chloride

Identification

Structural Formula
Germanium(IV) chloride
CAS:
10038-98-9
EINECS:
233-116-7
Molecular Formula:
Cl4Ge
MDL:
MFCD00011029
SMILES:
Cl[Ge](Cl)(Cl)Cl
Synonym:
tetrachloro-german ; germanium(+4)chloride ; germanium chloride ; germanium(iv) chloride ; tetrachloro-germane ; tetrachloro-germaniu ; tetrachlorogermane ; germane, tetrachloro- ; nsc 132053 ; germaniumchloride (gecl4) (6ci,7ci,8ci) ; germanium(IV) chloride ; gecl4 ; germane,tetrachloro- ; germanium tetrachloride


Description

Germanium(IV) chloride is a reagent in the preparation of colorless crystalline materials. Studies indicate that Germanium(IV) chloride can be used to study low valent germanium compounds. Biologically, Germanium(IV) chloride is useful as a catalyst used to convert carbohydrates into 5-hydroxymethylfurfural in ionic liquids. Furthermore, Germanium(IV) chloride is a useful intermediate in the solid phase synthesis of aromatic compounds such as chlorogermane linker 12.


Suppliers

Shandong Lanhai Industry Co.,Ltd.
SLIC217810890
Alchimica s.r.o.
AS10563168
Cerametek Materials (ShenZhen) Co., Ltd..
CM270610824
Fox Chemicals GmbH
FC11883564
Merck Schuchardt OHG
MSO13205280
Hangzhou Keying Chem Co., Ltd.
HKC19807920
Hangzhou Ocean Chemical Co., Ltd.
HOC21788712
Santa Cruz Biotechnology, Inc.
250053
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Gihi Chemicals Co., Limited
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Germanium(IV) chloride for optical fibre
Dayang Chem (Hangzhou) Co.,Ltd.
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Germanium(IV) chloride, 99.9999% (metals basis)
Alfa (A Johnson Matthey Company)
A752022560
Germanium(IV) chloride, 99.9999% (metals basis)
Ascender Chemical Co.,Ltd
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Germanium tetrachloride, 99.99%, (trace metal basis)
Acros Organics BVBA
AOB494019760

Prices & Availability




Data is processed


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Properties for Germanium(IV) chloride

Molecular Weight:
214.39 g·mol−1
Density:
1.844 g/mL at 25 °C
Melting point:
-49.5 °C
Boiling point:
83 °C(lit.)
Flash point:
83.1 °C
Solubility:
DECOMPOSES
Transport Information:
UN 3390
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Hazard Statements

GHS05

GHS05
Corrosive
  • Corrosive to metals, category 1
GHS07

GHS03
Harmful
  • Acute toxicity (oral, dermal, inhalation), category 4
  • Skin irritation, categories 2, 3
  • Eye irritation, category 2A
  • Skin sensitization, category 1
  • Specific target organ toxicity following single exposure, category 3
    - Respiratory tract irritation
    - Narcotic effects
  • Not used
  • with the "skull and crossbones" pictogram
  • for skin or eye irritation if:
  • the "corrosion" pictogram also appears
  • the "health hazard" pictogram is used to indicate respiratory sensitization

Safety & Transport Information

Poison by intravenous route. Mildly toxic by inhalation. A skin, severe eye, and mucous membrane irritant. Will react violently with water or steam to produce toxic and corrosive fumes. When heated to decomposition it emits toxic fumes of Cl−. See also GERMANIUM COMPOUNDS.
Risk Codes:
R14 - Reacts violently with water
R34 - Causes burns
R37 - Irritating to respiratory system
R40 - Limited evidence of a carcinogenic effect
R67 - Vapours may cause drowsiness and dizziness
Safety Codes:
S25 - Avoid contact with eyes
S26 - In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
S27 - Take off immediately all contaminated clothing
S36 - Wear suitable protective clothing
S36/37/39 - Wear suitable protective clothing, gloves and eye/face protection
S45 - In case of accident or if you feel unwell seek medical advice immediately (show the label where possible)
S8 - Keep container dry
Hazard Classes:
8
Hazard Symbols:
C
Hazard symbol C
RID/ADR certification :
UN 3390 6.1 / PG 1
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Alternative Distributors of [Germanium(IV) chloride]

Producers or manufacturers change the product range from time to time. The following companies
have appeared as suppliers in the past / currently not verified

Jinan Great Chemical Co., Ltd. | Jinan Haohua Industry Co., Ltd.

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MSDS:
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